Apatite, Phosphorite and Phosphate Rock

Apatite is the name of a group of phosphate minerals with similar chemical compositions and physical properties. They are an important constituent of phosphorite, a rock mined for its phosphorus content and used to make fertilizers, acids, and chemicals. Apatite has a relatively consistent hardness and serves as the index mineral for a hardness of five in the Mohs Hardness Scale. Specimens with excellent clarity and color are sometimes cut as faceted gemstones. Those with good color and translucence are cut as cabochons.

Apatite Crystals

Physical Properties

Apatite is best known for its use as an index mineral with a hardness of 5 in the Mohs Hardness Scale. It is usually green in color, but can be yellow, brown, blue, purple, pink, or colorless. These colors are often so vivid that apatite has frequently been cut as a gemstone. Apatite is a brittle material. It breaks by both fracture and cleavage, but the cleavage is generally indistinct. Hexagonal apatite crystals are sometimes found in igneous and metamorphic rocks.

Physical Properties of Apatite

Chemical Classification Phosphate
Color Green, brown, blue, yellow, violet, pink, colorless. Transparent specimens with excellent clarity and vivid color are used as gemstones.
Streak White
Luster Vitreous to subresinous
Diaphaneity Transparent to translucent
Cleavage Poor to indistinct
Mohs Hardness 5
Specific Gravity 3.1 to 3.3
Diagnostic Properties Color, crystal form, and hardness. Brittle, often highly fractured. Can be scratched with a steel knife blade.
Chemical Composition A group of calcium phosphates.
    Fluorapatite: Ca5(PO4)3F
    Hydroxylapatite: Ca5(PO4)3(OH)
  Chlorapatite: Ca5(PO4)3Cl
    Carbonate-rich apatite/francolite:
Crystal System Hexagonal
Uses Fertilizer, phosphoric acid, hydrofluoric acid, gemstones, ore of rare earth elements, pigments, gemstone. Serves as a hardness of 5 on the Mohs Hardness Scale.

Geologic Occurrence

Apatite forms under a wide variety of conditions and is found in igneous, metamorphic, and sedimentary rocks. The most important deposits of apatite are in sedimentary rocks formed in marine and lacustrine environments. There, phosphatic organic debris (such as bones, teeth, scales, and fecal material) had accumulated and was mineralized during diagenesis. Some of these deposits contain enough phosphorus that they can be mined and used to produce fertilizers and chemical products.

Apatite occasionally occurs as well-formed hexagonal crystals in hydrothermal veins and pegmatite pockets. These crystals often have a very high clarity and a vivid color and have been cut into gems for collectors. Mineral collectors also enjoy these well-formed apatite crystals, and the prices paid for them often exceeds their value as gem rough.

Phosphate Rock and Phosphorite

Phosphate rock and phosphorite are names used for sedimentary rocks that contain at least 15% to 20% phosphate on the basis of weight. The phosphorous content in these rocks is mainly derived from the presence of apatite minerals. Determining which apatite-group minerals are contained in the rock cannot be determined without laboratory testing because their particle sizes are so small.

Most phosphate rock has a non-detrital origin similar to limestone. Some of the phosphate is deposited by precipitation from solution; some is the remains and waste products of organisms; and, some is deposited by groundwater during diagenesis.
Like limestone, phosphate rock is deposited in sedimentary basins where the influx of detrital material is relatively low. That allows the phosphate to accumulate with very little dilution from other materials. Where the dilution rate is high, phosphatic shales, mudstones, limestones, and sandstones will form instead of phosphate rock.

Uses of Apatite as Phosphate Rock

Most of the phosphate rock mined throughout the world is used to produce phosphate fertilizer. It is also used to produce animal feed supplements, phosphoric acid, elemental phosphorous, and phosphate compounds for the chemical industry.
China is the largest producer of phosphate rock, producing approximately 100 million tons in 2014. The United States, Russia, Morocco, and Western Sahara are also major phosphate producers. Over 75% of the world's reserves of phosphate rock are located in Morocco and Western Sahara.

Phosphate rock is the only material that can be used to produce enough fertilizer to satisfy world demand. Without it, farmers would not be able to produce enough food to feed the world's population. It is surprising that one type of rock, a rock that most people know nothing about, is so important to keeping the world fed and alive.

Sources: Geology.com


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